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Websites</a></nav></aside><main><section><h5>Idaho INBRE Summer Research Conference: Moscow, Idaho</h5><h2>Measuring diffusion of protons in polyvinyalginate</h2><h3><small><a href=/people/thomas-a.-christensen-ii/ class="card-link
bolder"><span class="fa-container fa-fw"><svg xmlns="http://www.w3.org/2000/svg" viewBox="0 0 448 512"><path d="M224 256A128 128 0 10224 0a128 128 0 100 256zM448 512 384 304H64L0 512H448z"/></svg></span>
Thomas A. Christensen II</a>
<a href=/people/jonathan-counts/ class=card-link><span class="fa-container fa-fw"><svg xmlns="http://www.w3.org/2000/svg" viewBox="0 0 448 512"><path d="M224 256A128 128 0 10224 0a128 128 0 100 256zM448 512 384 304H64L0 512H448z"/></svg></span>
Jonathan Counts</a>
<a href=/people/james-g.-moberly/ class=card-link><span class="fa-container fa-fw"><svg xmlns="http://www.w3.org/2000/svg" viewBox="0 0 448 512"><path d="M224 256A128 128 0 10224 0a128 128 0 100 256zM448 512 384 304H64L0 512H448z"/></svg></span>
James G. Moberly</a></small></h3><h4>July 31, 2018</h4><p>Trichloroethylene (TCE) is a toxic and carcinogenic contaminant that presents
unique challenges for cleanup because of its density and volatility. Use of
microorganisms may be a promising remediation method, however metabolism of TCE
results in acid buildup, which consequently impedes the ability of
microorganisms to perform this remediation. Polyvinylalginate (PVA) shows
promise as a useful shield for microorganisms carrying out bioremediation of TCE
by surrounding them in a protective biofilm-like layer, however, key information
is missing which relates diffusion of TCE or its metabolic products through PVA.
To measure the effective diffusion coefficient of H<sup>+</sup>
ions through
a PVA membrane cross-linked with boric acid and calcium ions, we used a modified
diaphragm cell. We found the effective diffusion coefficient to be 1.40 ×
10<sup>-5</sup>
± 1.91 × 10<sup>-6</sup>
cm<sup>2</sup>
s, a nearly
seven-fold decrease in diffusivity compared to protons in water, with an
unexpected significant but as of yet unquantified adsorption capacity. These
results suggest that polyvinylalginate is effective in slowing diffusion of
protons and buffering these acids produced by trichloroethylene metabolism, and
remains suitable for encapsulation of microorganisms involved in bioremediation.</p></section></main></div><footer><img src=/graphics/brandedbull.min.svg height=95rem><p>&copy; 2018 Thomas A. Christensen II<br>Licensed
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